Gas-phase infrared spectrum and acidity of the radical cation of 9-methylguanine.

نویسندگان

  • Linda Feketeová
  • George N Khairallah
  • Bun Chan
  • Vincent Steinmetz
  • Philippe Maître
  • Leo Radom
  • Richard A J O'Hair
چکیده

Oxidative damage to DNA yields guanine radical cations. Their gas-phase IR spectroscopic signature and acidity have been modelled by the radical cation of 9-methylguanine. Comparisons with quantum chemistry calculations suggest that radical cation formation produces the ground-state keto tautomer, which has an N-H acidity enhanced by ~470 kJ mol(-1).

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عنوان ژورنال:
  • Chemical communications

دوره 49 66  شماره 

صفحات  -

تاریخ انتشار 2013